The October meeting in New Haven

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The February Meeting in New Haven

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New Haven , Connecticut 06511

The rapid, degenerate 1,2-hydride shift in 2,3-dimethyl-2-butyl cation in stable solution in SbF5/ S02C1F was perturbed by deuterium and 13C leading to splittings observed by 13C NMR spectros­ copy over a range of temperatures. Accurate values for equilibrium isotope effects were obtained from these data. Theoretical calculations of the equilibrium isotope effects were performed using the Gauss...

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ژورنال

عنوان ژورنال: Bulletin of the American Mathematical Society

سال: 1953

ISSN: 0002-9904

DOI: 10.1090/s0002-9904-1953-09652-5